Reductive displacement of allylic acetates by hydride transfer via catalytic activation by palladium(0) complexes

DOI: 10.1016/S0040-4039(00)93615-3

Source and publish data:

Tetrahedron Letters p. 27 - 30 (1980)

Update date:2022-08-02

Topics:

Authors:

Hutchins, Robert O.

Learn, Keith

Fulton, Robert P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)93615-3

Allylic acetates are reduced to alkenes by reductive displacement by hydride reagents via catalytic activation with Pd(0) complexes. In the absence of hydrides, allylic acetates afford conjugated dienes in DMSO solvent.

Full text of DOI:10.1016/S0040-4039(00)93615-3

Products guided by the article

Product name:6-((E)-Buta-1,3-dienyl)-1-methyl-cyclohexene

Cas No:74423-07-7

R&D Labs maybe for 74423-07-7

Tianjin Ji Ping Jia Chemical Co., Ltd.

Contact:18622448868

Address:tianjin
SHANDONG CREDAGRI CHEMICAL CO., LTD.

Contact:+86-531-88872050

Address:ROOM 601A, BUILDING 2, SHUNTAI SQUARE, NO. 2000 SHUNHUA ROAD, HI-TECH DEVELOPMENT ZONE, JINAN, CHINA.
Chemvon Biotechnology Co. Ltd.

website:http://www.chemvon.com

Contact:86-21-58550039;86-21-31268550-8004

Address:Suite B-10#, 6999 Chuansha Road, Pudong District, Shanghai 201202, China
Shantou Baokang Pharmaceutical Co., Ltd.

Contact:+86-754-88873487

Address:5/F B Block Huangshan Bldg Huangshan Rd Shantou
zhenjiang runjing high purity chemical co ltd

Contact:+86-511-83361155

Address:No.8.haixi road,international chemical park

Relevant to this article

One-pot, three-component synthesis of arylidenesuccinates and related compounds

Doi:10.1016/S0040-4039(97)01294-X
(1997)
Doi:10.1039/c39790000404
(1979)
Stereoselective chloroacetate aldol reactions: Syntheses of acetate aldol equivalents and darzens glycidic esters

Doi:10.1021/ol0490835
(2004)
Synthetic and mechanistic aspects of 4-substituted-3,5-bis(methoxycarbonyl)isoxazoline N-oxides and the corresponding 3,5-bis-(butylcarbamoyl)isoxazoles derived therefrom

Doi:10.1248/cpb.28.479
(1980)
The synthesis of oligonucleotides that contain 2,4-dinitrophenyl reporter groups

Doi:10.1016/0008-6215(92)84170-W
(1991)
Iodine-catalyzed formation of substituted 2-aminobenzothiazole derivatives in PEG₄₀₀

Doi:10.1039/c6ra15971k
(2016)

Article Doi