Reductive displacement of allylic acetates by hydride transfer via catalytic activation by palladium(0) complexes

DOI: 10.1016/S0040-4039(00)93615-3

Source and publish data:

Tetrahedron Letters p. 27 - 30 (1980)

Update date:2022-08-02

Topics:

Authors:

Hutchins, Robert O.

Learn, Keith

Fulton, Robert P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)93615-3

Allylic acetates are reduced to alkenes by reductive displacement by hydride reagents via catalytic activation with Pd(0) complexes. In the absence of hydrides, allylic acetates afford conjugated dienes in DMSO solvent.

Full text of DOI:10.1016/S0040-4039(00)93615-3

Products guided by the article

Product name:6-((E)-Buta-1,3-dienyl)-1-methyl-cyclohexene

Cas No:74423-07-7

R&D Labs maybe for 74423-07-7

Nanjing Chemzam Pharmtech Co., Ltd.

Contact:+86-25-86462165,+86-13915979898

Address:C5-1，6 Maiyue Road，Maigaoqiao，Nanjing，Jiangsu，China
Jinan Trio PharmaTech Co., Ltd

Contact:86-531-88811783；+(0)13153010282

Address:2766 Yingxiu Road, Jinan High-Tech Zone, China
Shanghai Hope Chem Co., Ltd

website:http://www.hope-chem.com

Contact:86-21-58090396-805

Address:Floor 4, Building 5, No.588 Tianxiong Road, Zhoupu International Medical Zone, ShangHai, China
Hubei anhuang chemical Co.Ltd

Contact:

Address:308# dongwu avenue dongxihu district wuhan city
Chongqing Werlchem Fine Chemical Co. Ltd

Contact:+86-23-67521957

Address:NO.15,Fortune Road,Yubei District,401121,Chongqing,China

Relevant to this article

One-pot, three-component synthesis of arylidenesuccinates and related compounds

Doi:10.1016/S0040-4039(97)01294-X
(1997)
Doi:10.1039/c39790000404
(1979)
Stereoselective chloroacetate aldol reactions: Syntheses of acetate aldol equivalents and darzens glycidic esters

Doi:10.1021/ol0490835
(2004)
Synthetic and mechanistic aspects of 4-substituted-3,5-bis(methoxycarbonyl)isoxazoline N-oxides and the corresponding 3,5-bis-(butylcarbamoyl)isoxazoles derived therefrom

Doi:10.1248/cpb.28.479
(1980)
The synthesis of oligonucleotides that contain 2,4-dinitrophenyl reporter groups

Doi:10.1016/0008-6215(92)84170-W
(1991)
Iodine-catalyzed formation of substituted 2-aminobenzothiazole derivatives in PEG₄₀₀

Doi:10.1039/c6ra15971k
(2016)

Article Doi