Tetrahedron p. 4719 - 4728 (1986)
Update date:2022-07-30
Topics:
Haufe, G.
Wolf, A.
Schulze, K.
Electrophilic additions of Broensted acids to 1,5-dimethylcycloocta-1,5-diene yield syn-8-substituted 1,5-dimethylbicyclo<3.2.1>octanes via parallel ?-cyclization and subsequent Wagner-Meerwein type rearrangements.The corresponding anti-isomers are synthesized by nucleophilic substitution in the 8-position.The classical or nonclassical structure of the cationic intermediates is discussed.
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Doi:10.5560/ZNB.2013-3020
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