The Synthesis of α-D-Galactopyranosyl and α-D-Mannopyranosyl 2-Amino-2-deoxy-α-D-glucopyranosides and the Conformation of Their Glycoside Linkage

Article abstract of DOI:10.1246/bcsj.54.2728

A new analog of trehalosamine, α-D-galactopyranosyl 2-amino-2-deoxy-α-D-glucopyranoside, was synthesized by the glycosylation of 2,3,4,6-tetra-O-(p-chlorobenzyl)-α-D-galactopyranose with 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitroanilino)-α-D-glucopyranosyl