
Tetrahedron Letters p. 573 - 576 (1980)
Update date:2022-08-02
Topics:
Binns, Malcolm R.
Haynes, Richard K.
Houston, Timothy L.
Jackson, W. Roy
One equivalent of HMPA induces 1,4-addition of the title anions predominantly through the α-position to cyclopentenone in THF at -78 deg C.In THF alone irreversible addition takes place to give mixtures comprising largely α- and γ-1,2 products.
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Doi:10.1248/cpb.28.479
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