Journal of the Chemical Society. Perkin transactions I p. 277 - 281 (1980)
Update date:2022-09-26
Topics:
Collins, Peter M.
Gupta, Paul
Travis, Anthony S.
Solutions of di-O-isopropylidene-β-D-erythro-2,3-hexodiulose-2,6-pyranose (8) in various solvents decarbonylate upon irradiation with u.v. light to give an anomeric mixture of 1,2:3,4-di-O-isopropylidene-D-ribulose (10) and (11), accompanied by variable amounts of the unstable olefin (12) and the aldehyde (13).Compound (13) was found to be a thermal breakdown product from the olefin (12).The photoproduct yields were sensitive to the solvent polarity.The furanose derivatives (10) and (11) were produced with a 1.2:1.0 ratio in 30, 35, and 45percent yields in methyl cyanide, benzene, and n-hexane, respectively.The D-ribulose derivatives (10) and (11) were produced on a preparative scale, isolated free from (12) and (13) by distillation, and hydrolysed to D-ribulose.
View MoreTangshan Wisdom Trading Co.,Ltd
Contact:86 315 2222979
Address:No.41 BeiXinXi Road, Yangguang building 1-1102 , Tangshan, Hebei, China
Binzhou Holly Pharmaceutical Co.,Ltd.
Contact:74517
Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China
Chemsigma International Co.,Ltd.
website:http://www.chemsigma.com
Contact:86-025-58748998
Address:Rm.705, 15th Building,Rd.Xinke II
Zhengzhou Yuanli Biological Technology Co., Ltd.
Contact:+86-371-67897870/67897895
Address:No. 38, Qingyang Street, Zhengzhou, Henan, China
Hangzhou LINGEBA Technology Co., Ltd.
Contact:+0086-571-87389059
Address:Office 1-913,NewYouth Plaza, GongShu Area, HangZhou,ZheJiang,P.R.China
Doi:10.1021/ja990632p
(1999)Doi:10.1246/cl.1999.745
(1999)Doi:10.1246/cl.1979.329
(1979)Doi:10.1039/c39860001399
(1986)Doi:10.1021/jo980022s
(1998)Doi:10.3390/ijms19103061
(2018)
