Journal of Fluorine Chemistry p. 93 - 99 (1992)
Update date:2022-08-04
Topics:
Suyama, T.
Kato, S.
Mizutani, Y.
The reaction of fluoroglyoxylic acid esters and fluoroformic acid esters with perfluoropropene (PFP) yielded perfluoro(3-methyl-2-oxobutyric) acid esters and perfluoroisobutyric acid esters, respectively.Oxamide derivatives and 2,3-quinoxalinediol have been prepared by the reaction of perfluoro(3-methyl-2-oxobutyric) acid esters with amines and o-phenylenediamine, respectively.Perfluoro(3-methyl-2-oxobutyric) acid esters give perfluoroisobutyric acid esters on heating in the presence of fluoride ion in an aprotic solvent.
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