Journal of Organic Chemistry p. 4953 - 4957 (1983)
Update date:2022-08-04
Topics:
Adcock, James L.
Evans, William D.
Heller-Grossman, Lilly
Aerosol direct fluorination of neopentyl chloride produces perfluoroneopentyl chloride in 74percent yields.Analogous fluorination of neopentyl bromide produces perfluoroisopentane in 63percent yield.Data are presented that support a carbocation rearrangement in the fluorination of neopentyl bromide.The carbocations are presumed to arise from disproportionation of neopentylbromine fluorides.
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