Journal of Organic Chemistry p. 4287 - 4292 (1980)
Update date:2022-08-05
Topics: Regioselectivity Stereoselectivity
Hoye, Thomas R.
Bottorff, Kyle J.
Caruso, Andrew J.
Dellaria, Joseph F.
N-Phenyltriazoline-3,5-dione reacts with α,β-unsaturated ketones,esters, and lactones 1a-l to give ene adducts 2a-l.The reactions usually proceed in good yield with high regioselectivity and, where possible, high stereoselectivity.Ene substrates capable of adopting an s-cis conformation show much greater reactivity.A variety of mechanistic interpretations is considered.
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