CYCLOPENTADIENYL-RUTHENIUM AND -OSMIUM CHEMISTRY. PART 11. REACTIONS AND STRUCTURES OF AND ITS TRIMETHYLPHOSPHINE ANALOGUE.

DOI: 10.1039/DT9810001398

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1398 - 1405 (1981)

Update date:2022-07-31

Topics:

Authors:

Bruce, Michael I.

Wong, Fook Sin

Skelton, Brian W.

White, Allan H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9810001398

The crystal structure of the title compound has been determined by single-crystal x-ray diffraction at 295 K and refined by least squares to a residual of 0.036 for 7 290 'observed' reflections.Crystals are triclinic, space group P<*>, with a = 14.493(8), b = 11.315(4), c = 11.745(4) Angstroem, α = 69.99(3), β = 84.67(4), γ = 62.27(3) deg, and Z = 2.The ruthenium environment is pseudo-tetrahedral, Ru-Cl 2.453(2), Ru-P 2.337(1), 2.335(1), 2.20₇ Angstroem.The phenyl ring environments are highly crowded and the nature of the steric interactions between them is examined.The structure of the trimethylphosphine analogue has also been determined, 1 805 'observed' reflections being refined to a residual of 0.059.Crystals are orthorombic, space group Pbca, with a = 29.251(8), b = 14.703(4), c = 14.649(7) Angstroem, and Z = 16.The two ruthenium enviroments are similar to that of the triphenylphosphine analogue.The Ru-Cl distances are 2.451(6), 2.440(5), and Ru-P 2.273(5)-2.280(6) Angstroem.The value of is 2.20 Angstroem.The syntheses and properties of and of the cationic derivatives ⁺ (L = MeCN, CO, CNBu^t, or PMe3) are also described.

Full text of DOI:10.1039/DT9810001398

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(η5-C5H5)Ru(PPh3)(PMe3)Cl

Cas No:74558-78-4

R&D Labs maybe for 74558-78-4

LINYI FUDE FINE CHEMICAL CO.,LTD

Contact:86-539-2361184

Address:YISHUI, LINYI,SAHNDONG,CHINA
ENERGYCO LTD.

Contact:+86-25-83719363

Address:106-7 Chunnan Rd, Chunxi Town, Gaochun, Nanjing, China
FUJIAN SHANSHUI CHEMICAL CORP.LTD.

Contact:+86-151-59920036

Address:Jinqiao Gareden, jo@fj-xinyi.com
NEW FORTUNE INDUSTRIAL CO.,LTD.

website:http://newfortune.lookchem.com/

Contact:+86-25-8645-9456

Address:C4-105 GREEN ISLAND FLOWER TOWN
Shanghai Topchem Co., LTD

website:http://www.shtopchem.com/

Contact:0086-0576-87776998

Address:room no 1608,xuhui business building yude road,xujiahui street, xuhui district

Relevant to this article

NBu₄NI-Catalyzed oxidative imidation of ketones with imides: Synthesis of α-amino ketones

Doi:10.1039/c3cc48887j
(2014)
REACTION DES TOSYLHYDRAZONES-COBALT(III)PORPHYRINES; SYNTHESE D'α-STYRYLCOBALT(III)PORPHYRINES

Doi:10.1016/S0022-328X(00)86081-7
(1980)
Synthesis of carbohydrate analogs (positional, configurational, and optical) of n-acetylmuramoyl-L-alanyl-D-isoglutamine, and their immunoadjuvant activities.

Doi:10.1016/S0008-6215(00)80713-2
(1981)
Br?nsted Acid-Catalyzed Intramolecular α-Arylation of Ketones with Phenolic Nucleophiles via Oxy-Allyl Cation Intermediates

Doi:10.1002/ejoc.202000169
(2020)
Polyaniline supported cobalt catalysed on pot stereoselective synthesis of the structural analogues of aminopeptidase inhibitor Bestatin

Doi:10.1016/S0040-4039(97)10172-1
(1997)
Doi:10.1016/S0040-4020(01)92514-1
(1966)

Article Doi