Journal of Organic Chemistry p. 4135 - 4139 (1980)
Update date:2022-08-05
Topics:
Whitesell, James K.
Helbling, Andre M.
β,γ-Unsaturated esters are of interest for the synthesis of mono- and sesquiterpenes where the alkene linkage is destined for cleavage to a dialdehyde as well as for the synthesis of γ-butyrolactones. A general method for the preparation of deconjugated esters of this type from allylic alcohols is described. The method is useful for the construction of β,γ-unsaturated esters where the ? bond is disubstituted and part of a cyclic array. The sequence works only poorly in acyclic systems.
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Doi:10.1021/ja00533a011
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(1980)
