S.-C. Hsu, Y.-C. Lin, S.-L. Huang, Y.-H. Liu, Y. Wang, H. Liu
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Empirical formula
Molecular mass
T (K)
C61H63N4P2RuS3
1111.34
295(2)
monoclinic
P21
11.55600(10)
18.0640(2)
13.33100(10)
90
97.5110(10)
90
2758.94(4)
2
1.338
1158
C48H56N2P2RuS
856.02
295(2)
triclinic
P1
13.3770(3)
18.4420(4)
20.4070(5)
110.9660(10)
90.8920(10)
111.2670(10)
4319.4(2)
4
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Crystal system
Space group
¯
[16]
[17]
[18]
˚
a (A)
˚
b (A)
˚
c (A)
[19]
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[21]
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α (°)
β (°)
γ (°)
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3
˚
V (A )
Z
ρ(calcd.) (Mg/m3)
F(000)
1.316
1792
Data/parameters
GOF
12253/641
1.112
0.0372, 0.0902
0.0458, 0.1032
14753/982
0.990
0.0595, 0.1314
0.1736, 0.1992
R1, wR2 [I Ͼ 2σ(I)][a]
(all data)
[24]
[25]
[a]
2
2 2
2 2 1/2
R1 ϭ Σ||Fo| Ϫ |Fc||/Σ|Fo|, wR2 ϭ [Σw(Fo Ϫ Fc ) / Σw(Fo ) ]
.
[26]
[27]
[28]
[29]
[30]
Acknowledgments
We thank the National Science Council of Taiwan for financial
support. Assistance to S. C. H. from The Bureau of Investigation,
Ministry of Justice, Taiwan, R. O. C. is also gratefully acknowl-
edged.
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G. M. Sheldrick, (1997), SHELXTL V5.1 Software Reference
Manual, Bruker AXS Inc., Madison, Wisconsin, USA.
Received August 19, 2003
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2004 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Eur. J. Inorg. Chem. 2004, 459Ϫ462