Journal of Organic Chemistry p. 1030 - 1037 (1993)
Update date:2022-08-02
Topics:
Majetich, George
Song, Jee-Seop
Leigh, Alistair J.
Condon, Stephen M.
An allylsilane-based annulation was used to construct a functionalized perhydroazulene.The C(1), C(5), and C(10) stereocenters, characteristic of the helenanolides, were established using a reductive alkylation strategy.Stereoselective syntheses of the pseudoguaianolides graveolide and aromaticin were achieved.
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