Journal of Organometallic Chemistry p. 33 - 40 (1980)
Update date:2022-08-03
Topics:
Issleib, Kurt
Schmidt, Harry
Meyer, Hinrich
Bis-silylated phosphines react with carbodiimides giving phosphaguanidines through insertion into the P-Si-bond.Depending on the substituents R' and R" the N,P-bis-silylated derivatives (I) or the N,N'-bis-silylated isomers (II) are formed, the latter results from P,N-silyl migration and formation of a P=C double bond.
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Doi:10.1039/b404150j
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(1980)Doi:10.1016/j.bmc.2014.12.057
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