Stereochemistry and Mechanism of the Copper(I) Halide Cleavage of Thallium-Carbon Bonds

DOI: 10.1016/0040-4039(80)80025-6

Source and publish data:

Tetrahedron Letters p. 2283 - 2286 (1980)

Update date:2022-08-03

Topics:

Authors:

Baeckvall, Jan-E.

Ahmad, Mesbah U.

Uemura, Sakae

Toshimitso, Akio

Kawamura, Takashi

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Article abstract of DOI:10.1016/0040-4039(80)80025-6

Stereochemical studies on the copper(I) halide cleveage of thallium-carbon bonds in acetonitrile indicate that at 80 deg C a radical path accounts for approximately 2/3 of the product, whereas at 60 deg C an ionic path predominates.The results are consist

Full text of DOI:10.1016/0040-4039(80)80025-6

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