Journal of Organic Chemistry p. 5286 - 5290 (1980)
Update date:2022-08-04
Topics:
Sekiguchi, Akira
Ando, Wataru
Pyrolysis of bis(trimethylsilyl)phenylmethanol gave (trimethylsilyl)phenylcarbene by the elimination of trimethylsilanol and the products were compared with those of (trimethylsilyl)phenyldiazomethane.Alkylsilylcarbenes obtained from the pyrolyses of 1,1-bis(trimethylsilyl)-1-alkanols afforded vinyltrimethylsilanes in high yields. (Trimethylsilyl)phenylmethanols were found to be excellent precursors of phenylcarbenes and their intramolecular reactions were also studied.
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Doi:10.1021/jo01314a060
(1980)Doi:10.1248/cpb.28.1578
(1980)Doi:10.1007/BF02943238
(1968)Doi:10.1124/mol.118.112359
(2018)Doi:10.1016/S0022-328X(00)86104-5
(1981)Doi:10.1021/jm00185a025
(1980)
