Dynamic Stereochemistry of Imines and Derivatives. Part 16. Conformation and Stereodynamics of Oxaziridines, Nitrones, and Imines containing the N-(1-Mesitylethyl) or (1-Pentamethylphenylethyl) Group; a Nuclear Magnetic Resonance and X-Ray Crystallographi

DOI: 10.1039/P29840000095

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Journal of the Chemical Society. Perkin transactions II p. 95 - 100 (1984)

Update date:2022-07-30

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Authors:

Boyd, Derek R.

McCombe, Kenneth M.

Hamor, Thomas A.

Jennings, W. Brian

Wilson, Valerie E.

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Article abstract of DOI:10.1039/P29840000095

The (1)H n.m.r. chemical shift nonequivalence of the ortho-methyl groups in eight title compounds observed at or below ambient temperature is assigned to slow rotation about the aryl-CHMe bond.The rotational barriers (8-17 kcal mol^-1) were eval

Full text of DOI:10.1039/P29840000095

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