Journal of Organic Chemistry p. 5225 - 5227 (1980)
Update date:2022-08-02
Topics:
Liu, Paul S.
Marquez, Victor E.
Kelley, James A.
Driscoll, John S.
Syntheses of the novel seven-membered-ring (+-)-5-hydroxy-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one (8) and its 1-β-D-ribofuranosyl nucleosides 4a and 4b have been accomplished by adaption of the transpositional allylic oxidation procedure following the electrophilic addition of ArSeOH to the corresponding starting olefins 5 and 11.
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