INFLUENCE DU GROUPEMENT METHOXYLE EN C-1 DANS L'ORIENTATION DE LA REDUCTION DES METHYL-HEXOPYRANOSID-2-ULOSES PAR LE BOROHYDRURE DE SODIUM

Article abstract of DOI:10.1016/S0008-6215(00)85431-2

Methyl 3,4-dideoxy- and -3,4,6-trideoxyhexopyranosiduloses were synthesized by two reaction pathways.The α anomers were stereoselectively reduced by sodium borohydride to give compounds having the α-erythro configuration.Under the same conditions, the β a