Reactions of the 2-Allylbenzyl Radical: Relative and Absolute Rate Constants for Abstraction of Hydrogen Atom from Thiophenol, Dicyclohexylphosphine, Phenols, and Arylalkyl Donors

DOI: 10.1021/jo00359a013

Source and publish data:

Journal of Organic Chemistry p. 1446 - 1456 (1986)

Update date:2022-08-02

Topics:

Authors:

Franz, James A.

Alnajjar, Mikhail S.

Barrows, Russell D.

Kaisaki, David L.

Camaioni, Donald M.

Suleman, Naushadali K.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00359a013

Relative and absolute rate expressions for hydrogen atom abstraction (k_abs) by the 2-allylbenzyl radical from thiophenol, dicyclohexylphosphine, and a series of alkyl-substituted aromatic hydrogen donors realative to exo cyclization to the 2-in

Full text of DOI:10.1021/jo00359a013

Products guided by the article

Product name:Methyl, [2-(2-propenyl)phenyl]-

Cas No:75421-42-0

R&D Labs maybe for 75421-42-0

ANHUI CHEM-BRIGHT BIOENGINEERING CO.,LTD

Contact:86-561-4080321

Address:No.8 Lieshan Industrial Zone of Huaibei
shanghai Tauto Biotech Co., Ltd

website:http://www.tautobiotech.com/en/index.htm

Contact:+86-21-51320588 ext. 8025

Address:No. 326, Aidisheng Rd , Zhangjiang Hi-tech Park, Shanghai , P.R.CHINA
WuHan rongfashun BioChemical co., LTD

Contact:02788866139

Address:No.95 LuoYu Road,Wuhan
NOVASYNCS CO., LTD

Contact:0512-63006287

Address:no.88.YISHENG Road,etdz-WUJIANG,SUZHOU,CHINA
Taizhou Sunny Chemical Co.,Ltd

Contact:+86-523-86920899 +86-13951172783

Address:No.11 Xingyuang road, Gaoyong Chemical Industry Park, Gaogang Jiangsu China

Relevant to this article

Imidazole-derived 2-[N-carbamoylmethyl-alkylamino]acetic acids, substrate-dependent modulators of insulin-degrading enzyme in amyloid-β hydrolysis

Doi:10.1016/j.ejmech.2014.04.009
(2014)
Utilization of Copper-Catalyzed Carboarylation-Ring Closure for the Synthesis of New Oxazoline Derivatives

Doi:10.1021/acs.orglett.5b01860
(2015)
Palladated oligophenylene thioethers: Synthesis and reactivity toward isocyanides, carbon monoxide, and alkynes

Doi:10.1021/om200607h
(2011)
Discovery of a potent, selective, and orally active phosphodiesterase 10A inhibitor for the potential treatment of schizophrenia

Doi:10.1021/jm500073h
(2014)
Synthesis and characterization of Cu(II), Ni(II), Co(II), Mn(II), and Cd(II) transition metal complexes of tridentate schiff base derived from O-vanillin and N-aminopyrimidine-2-thione

Doi:10.1080/10426507.2011.553501
(2011)
Chemoselective Rh-catalyzed allylic alkylations of chelated enolates using dienylcarbonates

Doi:10.1002/ejoc.201100350
(2011)

Article Doi