
Journal of the Chemical Society. Chemical communications p. 370 - 372 (1980)
Update date:2022-08-02
Topics:
Benschop, Hendrik P.
Konings, Cornelis A. G.
Platenburg, Dominique H. J. M.
Deen, Rudolf
Irradiation (254 nm) of (MeO)2P(S)SMe in ROH yields mainly (66 percent, R = Pri) the ionic photosolvolysis product (MeO)2P(S)OR with very low capture ratio 1.9 +/- 0.4 for R = Me vs.R = Pri under competitive photosolvolysis conditions, whereas irradiation in e.g. tetrahydrofuran and CH2Cl2 gives free-radical products, suggesting that the photoreactions proceed by way of an 'intimate radical-ion pair.'
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