An Electrically Neutral ?-Sulfuranyl Radical from the Homolysis of a Perester with Neighboring Sulfenyl Sulfur: 9-S-3 Species

DOI: 10.1021/ja00546a019

Source and publish data:

Journal of the American Chemical Society p. 7753 - 7759 (1980)

Update date:2022-08-02

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Authors:

Perkins, C. W.

Martin, J. C.

Arduengo, A. J.

Lau, W. Lau, W.

Alegria, A.

Kochi, J. K.

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Article abstract of DOI:10.1021/ja00546a019

The cyclic sulfuranyl radical 2 is generated by the low-temperature photolysis of tert-butylperoxy 2-(methylsulfenyl)benzoate (1) in methylene chloride solutions.The ESR spectrum of 2, centered at = 2.008₀, shows proton hyperfine splitting

Full text of DOI:10.1021/ja00546a019

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