Journal of the Chemical Society, Dalton Transactions p. 1698 - 1702 (1980)
Update date:2022-08-02
Topics:
Mascharak, Pradip K.
Chakravorty, Animesh
Triarylphosphines split the halogen bridge of the title complex and also open the arylazo-oximato chelate ring at the azo-end.In solution an equilibrium exists between the closed-ring and open-ring species.The equilibrium constants are reported.Bidentate phosphine and phosphinoarsine simultaneously split the bridge and cleave the Pd-N(azo) bond.Anhydrous HCl gas protonates the oximato-group with its concomitant displacement by Cl-ion; in effect the Pd-N(oxime) bond is selectively cleaved.
View MoreContact:+1-284-4950244
Address:Box 3069, Road Town, Tortola, British Virgin Islands
Haitong Chemical Industrial Co.,Ltd.
website:https://www.haitonglongwin.com/
Contact:+86-022-66221018
Address:18-701, No.99, The 4th Street, TEDA,
Shanghai shibo Chemical Co., Ltd
Contact:+86-021-60753516
Address:688 Qiushi Road, Jinshan High-tech Park, Shanghai, China,201512
Changzhou Pesan Chemical Co.,Ltd
website:http://www.pesanchem.com
Contact:+86 021 61559630
Address:No.7-9,Guanghua St.,Zhonglou District,Changzhou,China
ZHANGJIAGANG FREE TRADE ZONE YONG HAN INTERNATIONAL TRADING CO., LTD(expird)
Contact:86 512 57910558
Address:qianjin M road
Doi:10.1021/jo00315a009
(1981)Doi:10.1002/ejoc.200700670
(2007)Doi:10.1021/ja01299a043
(1936)Doi:10.1021/ic50217a010
(1981)Doi:10.1016/S0040-4039(00)77419-3
(1980)Doi:10.1016/S0040-4039(00)78666-7
(1980)
