Journal of the Chemical Society, Dalton Transactions p. 1698 - 1702 (1980)
Update date:2022-08-02
Topics:
Mascharak, Pradip K.
Chakravorty, Animesh
Triarylphosphines split the halogen bridge of the title complex and also open the arylazo-oximato chelate ring at the azo-end.In solution an equilibrium exists between the closed-ring and open-ring species.The equilibrium constants are reported.Bidentate phosphine and phosphinoarsine simultaneously split the bridge and cleave the Pd-N(azo) bond.Anhydrous HCl gas protonates the oximato-group with its concomitant displacement by Cl-ion; in effect the Pd-N(oxime) bond is selectively cleaved.
View MoreSuZhou Hua-Emy Chemical Import and Export Co., LTD.
Contact:+86-512-88804994; +86-512-88804550;
Address:710, Building B, International Trade Center, 12 Huanghelu, Changshu, Jiangsu,China
Shanghai WinTide BioTechnology Co.,Ltd
Contact:86-21-37100630
Address:No. 908 Yunhe Road, Fengxian district, Shanghai
Changzhou Welton Chemical Co., Ltd,
Contact:0086-519-85910828,85920537,85912897
Address:No.8 Jinlong Road, Binjiang Park, Changzhou, Jiangsu, China.
Contact:+86-574-87065746
Address:10th Floor, No.787 Baizhang East Road,
Shanghai Forever Biotech Co., Ltd.
Contact:+86-21-69734790
Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.
Doi:10.1021/jo00315a009
(1981)Doi:10.1002/ejoc.200700670
(2007)Doi:10.1021/ja01299a043
(1936)Doi:10.1021/ic50217a010
(1981)Doi:10.1016/S0040-4039(00)77419-3
(1980)Doi:10.1016/S0040-4039(00)78666-7
(1980)
