Journal of the Chemical Society. Chemical communications p. 558 - 559 (1980)
Update date:2022-08-04
Topics:
Gassman, Paul G.
Miura, Takashi
Mossman, Allen
Treatment of certain benzylic selenonium salts with a variety of bases resulted in nucleophilic attack to yield either an alkylation or a benzylation of the base, while the use of sodium amide in liquid ammonia as base generated a selenonium ylide which gave ortho substitution of the benzyl group via <2,3>sigmatropic rearrangement.
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