Journal of Organic Chemistry p. 509 - 515 (1981)
Update date:2022-08-06
Topics:
Kohda, Akira
Ueda, Keiko,
Sato, Tadashi
Under photooxidation in pyridine in the presence of FeCl3, mono- and disubstituted olefins gave α-chloro ketones, while tri- and tetrasubstituted olefins gave dichloro ketones with a C-C bond cleavage.The reaction was interpreted in terms of an electron-transfer mechanism occurring within the coordination sphere of the iron ion
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