ASYMMETRIC INDUCTION IN THE SIGMATROPIC REARRANGEMENT VIA CHIRAL AMMONIUM YLIDES

DOI: 10.1246/cl.1980.1077

Source and publish data:

Chemistry Letters p. 1077 - 1080 (1980)

Update date:2022-07-30

Topics:

Authors:

Hiroi, Kunio

Nakazawa, Kumiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1980.1077

The asymmetric <2,3> sigmatropic rearrangements of the chiral ammonium chlorides (E)-(3a,b) were achieved upon treatment with t-BuOK followed by acidic hydrolysis of the aminonitriles (5a,b) obtained to give (R)-(+)-2-methyl-2-phenyl-3-butenal (6).The rea

Full text of DOI:10.1246/cl.1980.1077

Products guided by the article

Product name:(S)-2-Benzyloxymethyl-1-((Z)-3-phenyl-but-2-enyl)-pyrrolidine

Cas No:76076-42-1

R&D Labs maybe for 76076-42-1

A.M FOOD CHEMICAL CO., LIMITED

Contact:86-531-87100375

Address:20Floor，Bblock，1Building，pharma-valley，Jinan，China
Hunan Haili Chemical Industry Co.,Ltd.

Contact:+86-731-85521860

Address:No.251, 2nd Section, Furong Road, Changsha,Hunan,China
ZHEJIANG SYNOSE TECH CO.,LTD.

website:https://www.synose.com/

Contact:86-579-82275537

Address:No.1958 Liyu Road , jinhua,zhejiang,China
Zhejiang Kente Chemical Co.,Ltd.

Contact:86-0576-87651912

Address:No.7, Fengxi West Road, Modern Industrial Zone
Huaian Double Win Chemicals Co.,Ltd.

Contact:+86-13511538872

Address:Blk 43,Greenland Century Town,Huaian District, Huaian City,Jiangsu Province,China

Relevant to this article

Enantioselective synthesis of primary 1-(aryl)alkylamines by nucleophilic 1,2-addition of organolithium reagents to hydroxyoxime ethers and application to asymmetric synthesis of G-protein-coupled receptor ligands

Doi:10.1021/jo049517+
(2004)
Doi:10.1002/hlca.19520350405
(1952)
Doi:10.1021/ja01325a045
(1934)
Mannich reaction of dihydropyridine derivatives. I. Reactions with secondary amines

Doi:10.1248/cpb.28.3163
(1980)
An Example of an N-Acetyl Group More Labile to Methanolic Hydrogen Chloride than an Analogous N-tert-Butoxycarbonyl Group. β-Acetyl- and β<<(Alkoxycarbonyl)amino>oxy>-α-N-acetyl-D-alanine Butylamides

Doi:10.1021/jo00321a039
(1981)
Doi:10.1002/hlca.19570400525
(1957)

Article Doi