Efficient Stereocontrolled Total Syntheses of Racemic and Natural Brefeldin-A

DOI: 10.1021/ja00384a038

Source and publish data:

Journal of the American Chemical Society p. 5473 - 5483 (1982)

Update date:2022-09-26

Topics:

Authors:

Drian, Claude Le

Greene, Andrew E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00384a038

Brefeldin-A, an antiobiotic fungal metabolite, has been obtained in both racemic and natural forms through a direct approach that employs norbornenone and 6-heptyn-2-ol as the basic starting materials.

Full text of DOI:10.1021/ja00384a038

Products guided by the article

Product name:n-butyl (<1R^*,2S^*,4S^*>-2-<(1E)-6-((tert-butyldimethylsilyl)oxy)-1-heptenyl>-4-hydroxycyclopentyl)acetate

Cas No:76101-86-5

R&D Labs maybe for 76101-86-5

Hubei Lingsheng Pharmaceuticals Co., Ltd.

Contact:+86-0710-3538058

Address:Xiangyang City Xiangcheng Economic Development Zone, Hubei Province
Guangzhou Reachin Chemical Co., Ltd

Contact:+86-20-37087379 ext.604

Address:A122C-1, Tianyuan Plaza, 401 Tianyuan Rd., Tianhe, Guangzhou, China
JiangXi Hong Run Chemical Co., Ltd

Contact:+86-0791-88521351

Address:XingHuo industrial zone in YongXiu county
Shandong Yuanli Science and Technology Co., Ltd.

Contact:86-0536-6777557

Address:Zhuliu Industiral Park,Changle County
Zhushan County Tianxin Pharmaceutical & Chemical Co., Ltd.

Contact:0086-719-4224892

Address:Tutang Road, Chengguan Town, Zhushan County, Hubei Province

Relevant to this article

An approach to 11β-isopropoxymethyl steroids

Doi:10.1002/recl.19800991004
(1980)
Chloro(dimethylamido) compounds of tantalum(V): Preparations, properties, and structures of [Ta(NMe₂)₃Cl₂]₂, TaCl₃(NMe₂)₂(HNMe₂), Ta(NMe₂)₃Cl₂(HNMe₂), and [TaCl₂(NMe₂)₂(HNMe₂)]₂O

Doi:10.1021/ic50220a049
(1981)
SYNTHESIS OF β-(cis-3-AMINOCYCLOHEXYL)- AND β-(trans-4-AMINOCYCLOHEXYL)PROPIONIC ACIDS AND THEIR DERIVATIVES

Doi:10.1007/BF00949228
(1980)
Synthesis of indenoquinolinone through aryne-mediated Pd(II)-catalysed remote C–H activation

Doi:10.1007/s11164-020-04387-2
(2021)
REACTION OF D-MANNOSE ARYLHYDRAZONES WITH DIMETHYL ACETYLENEDICARBOXYLATE: SYNTHESIS OF PENTAHYDROXYPENTYLPYRAZOLES

Doi:10.1016/S0008-6215(00)81889-3
(1982)
Steroid nitrogen compounds. I. Synthesis, structure, and properties of methyl 3alpha,7alpha-diacetoxy-11alpha-chloro-12alpha-nitro-5beta-cholanoate.

Doi:10.1016/S0039-128X(70)80068-X
(1970)

Article Doi