Synthesis of 1,3-Enynols and 1,2,4-Trienols via Allenic and Propargylic Borane Intermediates

DOI: 10.1021/jo00317a044

Source and publish data:

Journal of Organic Chemistry p. 829 - 830 (1981)

Update date:2022-09-26

Topics:

Authors:

Zweifel, George

Pearson, Norman R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00317a044

Sequential treatment of lithium chloropropargylide 1 with thexylalkenylchloroboranes and aldehydes affords, depending on the reaction conditions, 1,3-enynols or 1,2,4-trienols.

Full text of DOI:10.1021/jo00317a044

Products guided by the article

Product name:(E)-8-Phenyl-oct-7-en-5-yn-3-ol

Cas No:76174-04-4

R&D Labs maybe for 76174-04-4

Shanghai Dano Pharmaceutical Co.,Ld.(expird)

Contact:+86-592-6266840

Address:Building 1 Room 512, 720 Cailun Rd, Zhangjiang High-Tech Park, Shanghai 201203, China
Shanghai Surseechem Co.,Ltd.

Contact:+86-21-61318535

Address:Building 29,No.2139 Xizha Road, Fengxian District, Shanghai
Shandong Shouguang Songchuan Industrial Additives Co.,Ltd

Contact:+86-536-8566856

Address:Shouguang,Shandong,China
Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
Zhengzhou Yuanli Biological Technology Co., Ltd.

Contact:+86-371-67897870/67897895

Address:No. 38, Qingyang Street, Zhengzhou, Henan, China

Relevant to this article

Quinazolinone-based fungal efflux pump inhibitors. Part 1: Discovery of an (N-methylpiperazine)-containing derivative with activity in clinically relevant Candida spp.

Doi:10.1016/j.bmcl.2004.07.070
(2004)
Synthesis of optically active leukotriene (SRS-A) intermediates

Doi:10.1016/S0040-4039(00)93678-5
(1980)
Studies Dealing with the Intramolecular Ene Reaction of Cyclopropene Derivatives

Doi:10.1021/ja00292a042
(1985)
Gallium(III) chloride catalyzed stereoselective synthesis of E-configured α,β-unsaturated ketones

Doi:10.1055/s-2007-970760
(2007)
Dissociative ionization of aryl-substituted vinyl bromides in the gas phase: Experimental and computational evidence for the formation of stable α-arylvinyl cations both by direct means and spontaneous exothermic isomerization of unstable isomeric ions

Doi:10.1021/ja00400a047
(1981)
A stereospecific total synthesis of (±)-epipentenomycin I, (±)-epipentenomycin II and (±)-epipentenomycin III

Doi:10.1016/0040-4039(80)88095-6
(1980)

Article Doi