Molybdenum and Tungsten Complexes with Side-on Co-ordinated SPPh2-Ligands. X-Ray Crystal Structure Determination of Mo(CO)2(PPh3)(η2-SPPh2)2CH2Cl2

DOI: 10.1039/c39800000832

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 832 - 833 (1980)

Update date:2022-08-02

Topics:

Authors:

Ambrosius, Huub P. M. M.

Noordik, Jan H.

Ariaans, Gerry J. A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39800000832

M(CO)3Cl(η⁵-C5H5) and M(CO)3(PPh3)2Cl2 (M = Mo, W) react with SPPh2H and Et3N to give M(CO)2(η⁵-C5H5)(η²-SPPh2) and M(CO)2(PPh3)(η²-SPPh2)2, respectively; an X-ray crystal structure determination of Mo(CO)2(PPh3)(SPPh2)2 reveals a 7-co-ordinate pseudopentagonal bipyramidal geometry for the molybdenum atom with an almost planar configuration for the sulphur and phosphorus atoms.

Full text of DOI:10.1039/c39800000832

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:W(CO)2(P(C₆H₅)3)[SP(C₆H₅)2]2

Cas No:76374-49-7

R&D Labs maybe for 76374-49-7

zonk drug r&d limited

Contact:+86-20-32051076

Address:1105,Building A, International Business Incubator,Science City
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.

Contact:+86-186-02659358

Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China
Shandong Xiangde Biotechnology Co., Ltd

Contact:+86 -15066639877

Address:Sanba street
Hangzhou utanpharma Co., Ltd

Contact:86-571-87758773

Address:Room604 ,6F, Block A1-3 Xixi Plaza,No. 588 Wenyi West RD, Hangzhou,310012, China
Shanghai Kangxin Chemical Co., Ltd

Contact:+86 21 60717227

Address:118,Ganbai Village,Waigang Town,Jiading District,Shanghai

Relevant to this article

Synthesis, physicochemical properties, anticonvulsant activities, and GABA-ergic and voltage-sensitive calcium channel receptor affinities of α- substituted N-benzylamides of γ-hydroxybutyric acid¹) part 4: Search for new anticonvulsant compoun

Doi:10.1002/(SICI)1521-4184(19995)332:5<167::AID-ARDP167>3.0.CO;2-N
(1999)
Stereoselective synthesis of allyl ethers using α,β-unsaturated acylsilanes

Doi:10.1016/j.tetlet.2017.01.054
(2017)
Doi:10.1039/DT9770000397
()
Solvent-free, mild, facile, and rapid one-pot three-component synthesis of some novel imidazo[2,1-b]naphtho[1,2-e][1,3] thiazin-10-ones using p-TSA

Doi:10.1080/17415993.2014.885031
(2014)
New functional cyclic aminomethylphosphine ligands for the construction of catalysts for electrochemical hydrogen transformations

Doi:10.1002/chem.201304234
(2014)
Doi:10.1246/bcsj.38.513
(1965)

Article Doi