Molybdenum and Tungsten Complexes with Side-on Co-ordinated SPPh2-Ligands. X-Ray Crystal Structure Determination of Mo(CO)2(PPh3)(η2-SPPh2)2CH2Cl2

DOI: 10.1039/c39800000832

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 832 - 833 (1980)

Update date:2022-08-02

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Authors:

Ambrosius, Huub P. M. M.

Noordik, Jan H.

Ariaans, Gerry J. A.

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Article abstract of DOI:10.1039/c39800000832

M(CO)3Cl(η⁵-C5H5) and M(CO)3(PPh3)2Cl2 (M = Mo, W) react with SPPh2H and Et3N to give M(CO)2(η⁵-C5H5)(η²-SPPh2) and M(CO)2(PPh3)(η²-SPPh2)2, respectively; an X-ray crystal structure determination of Mo(CO)2(PPh3)(SPPh2)2 reveals a 7-co-ordinate pseudopentagonal bipyramidal geometry for the molybdenum atom with an almost planar configuration for the sulphur and phosphorus atoms.

Full text of DOI:10.1039/c39800000832

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