REACTIVITY OF THALLIUM TRIS MERCURATE

DOI: 10.1016/0022-328X(83)85045-1

Source and publish data:

Journal of Organometallic Chemistry p. 135 - 144 (1983)

Update date:2022-08-02

Topics: Reactivity Experimental Chemical compound Thallium Mercury

Authors:

Razuvaev, G. A.

Bochkarev, M. N.

Pankratov, L. V.

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Article abstract of DOI:10.1016/0022-328X(83)85045-1

Metallic lithium and dibenzenechromium displace thallium from (R3^fGe)3HgTl*1.5DME (R^f = C6F5, DME = 1,2-dimethoxyethane) to give (R3^fGe)3HgLi*3DME and <(R3^fGe)4Hg>2, respectively.Reactions of thallium germylmercurate with halides of metals and organometallics in DME/EtOH solution produce ionic compounds of <(R3^fGe)3Hg>^-M⁺ type, which (depending on M ) (a) may be isolated as pure compounds, (b) disproportionate, (c) form covalent derivatives R3^fGe-m or (d) undergo alcoholysis.A general scheme for the reactions has been proposed.

Full text of DOI:10.1016/0022-328X(83)85045-1

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