REACTIVITY OF THALLIUM TRIS MERCURATE

DOI: 10.1016/0022-328X(83)85045-1

Source and publish data:

Journal of Organometallic Chemistry p. 135 - 144 (1983)

Update date:2022-08-02

Topics: Reactivity Experimental Chemical compound Thallium Mercury

Authors:

Razuvaev, G. A.

Bochkarev, M. N.

Pankratov, L. V.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(83)85045-1

Metallic lithium and dibenzenechromium displace thallium from (R3^fGe)3HgTl*1.5DME (R^f = C6F5, DME = 1,2-dimethoxyethane) to give (R3^fGe)3HgLi*3DME and <(R3^fGe)4Hg>2, respectively.Reactions of thallium germylmercurate with halides of metals and organometallics in DME/EtOH solution produce ionic compounds of <(R3^fGe)3Hg>^-M⁺ type, which (depending on M ) (a) may be isolated as pure compounds, (b) disproportionate, (c) form covalent derivatives R3^fGe-m or (d) undergo alcoholysis.A general scheme for the reactions has been proposed.

Full text of DOI:10.1016/0022-328X(83)85045-1

Products guided by the article

Product name:[Cl₃Hg]^(1-)*[Cr(C₆H₆)2]⁽¹⁺⁾=[Cl₃Hg][Cr(C₆H₆)2]

Cas No:76857-82-4

R&D Labs maybe for 76857-82-4

Rugao Jinling Chemical Co., Ltd.(expird)

Contact:0086-513-68005586

Address:Lianluo new village huangshi town Rugao city Jiangsu Province.
Haitong Chemical Industrial Co.,Ltd.

website:https://www.haitonglongwin.com/

Contact:+86-022-66221018

Address:18-701, No.99, The 4th Street, TEDA,
Shanghai better-in Medical Technology Co.,LTD.

Contact:+86-21-38921049

Address:Lane 720 zhangjianggaoke cailun road, Pudong, Shanghai, room 513
Yangling Ciyuan biotech Co., Ltd.

Contact:86-15802970736

Address:2-1804, International Park Mansion, No.2, South Fengdeng Road, Lianhu District
Yangling Ciyuan biotech Co., Ltd.

Contact:86-15802970736

Address:2-1804, International Park Mansion, No.2, South Fengdeng Road, Lianhu District

Relevant to this article

Doi:10.1021/jo01347a027
(1966)
Two-photon absorption in three-dimensional chromophores based on [2.2]-paracyclophane

Doi:10.1021/ja038743i
(2004)
Oxidation of benzylic alcohols and ethers to carbonyl derivatives by nitric acid in dichloromethane

Doi:10.1002/ejoc.200390090
(2003)
AN ESR INVESTIGATION ON GROUP IVB ORGANOMETALLOXY- AND ORGANOMETALTHIO-PYRYL AND THIAPYRYL RADICALS

Doi:10.1016/0040-4020(80)88030-6
(1980)
Substrates to study the mechanism of vitamin D hydroxylation: Synthesis of 25-R-[26-²H₃]-cholecalciferol

Doi:10.1016/S0040-4039(00)77862-2
(1980)
C-20 stereospecific introduction of a steroid side chain

Doi:10.1021/ja00395a085
(1981)

Article Doi