Journal of the Chemical Society. Chemical communications p. 1244 - 1245 (1980)
Update date:2022-09-26
Topics:
Gani, David
Johnson, Alan W.
Lappert, Michael F.
Anaerobic irradiation of 2',3'-O-isopropylidene-8-phenylthio-5'-deoxyadenosine in the presence of t-butyl hydroperoxide causes rapid conversion into the 5',8-cycloadenosine, formed by reaction of the C(8)-radical with the neighbouring 5'-methyl group; this provides an in vitro analogy for the functionalisation of this methyl group involved in many of the coenzyme B12-controlled rearrangement reactions.
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Doi:10.1016/S0040-4020(01)82277-8
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(1984)
