Tetrahedron Letters p. 4105 - 4108 (1980)
Update date:2022-08-03
Topics:
Tamao, Kohei
Kakui, Toshio
Kumada, Makoto
(E)-Alkenylpentafluorosilicates, obtainable from acetylenes via hydrosilylation-silicate formation, react with alcohols in the presence of a catalytic amount of copper(II) acetate under an atmosphere of air (oxygen) at room temperature to form (E)-alkenyl ethers stereoselectively in satisfactory yields.Similar reaction with water gives aldehydes.
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(1980)
