Tetrahedron Letters p. 4105 - 4108 (1980)
Update date:2022-08-03
Topics:
Tamao, Kohei
Kakui, Toshio
Kumada, Makoto
(E)-Alkenylpentafluorosilicates, obtainable from acetylenes via hydrosilylation-silicate formation, react with alcohols in the presence of a catalytic amount of copper(II) acetate under an atmosphere of air (oxygen) at room temperature to form (E)-alkenyl ethers stereoselectively in satisfactory yields.Similar reaction with water gives aldehydes.
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Doi:10.1016/j.bmcl.2019.05.023
(2019)Doi:10.1002/ejoc.200700310
(2007)Doi:10.1016/j.tet.2004.06.099
(2004)Doi:10.1016/j.poly.2004.03.026
(2004)Doi:10.1021/jo00326a055
(1981)Doi:10.1016/S0040-4039(00)77842-7
(1980)
