The Oxidoreductive 1,3-Rearrangement of 3H-1,4-Benzodiazepines with Semicyclic Hydroxyamidine Structure to 2-Alkylamino-3-acyloxy-3H-1,4-benzodiazepines

DOI: 10.1002/ardp.19803131106

Source and publish data:

Archiv der Pharmazie p. 926 - 936 (1980)

Update date:2022-07-31

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Authors:

Schecker, Heinz-Guenther

Zinner, Gerwalt

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Article abstract of DOI:10.1002/ardp.19803131106

On treatment of N-alkyl-N-(3H-1,4-benzodiazepin-2-yl)-hydroxylamines with carboxylic anhydrides or chlorides an oxidoreductive rearrangement is observed in the presence of protons that leads to 1,4-benzodiazepines bearing the acylated hydroxylaminic oxyge

Full text of DOI:10.1002/ardp.19803131106

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