Journal of the Chemical Society. Perkin transactions I p. 2566 - 2569 (1981)
Update date:2022-08-03
Topics:
Pellicciari, Roberto
Fringuelli, Renata
Sisani, Ettore
Curini, Massimo
α-Diazo-β-hydroxyketones, obtained by condensation of aldehydes with 1-diazo-1-lithioacetone, are efficiently transformed into the corresponding β-diketones by exposure to rhodium(II) acetate, The sequence is applied to a new synthesis of β-damascone (10).
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Doi:10.1002/ejoc.200400307
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(1980)
