Reduction-Oxidation Properties of Organotransition-metal Complexes. Part 10. Formation and Reactivity of the Paramagnetic Cyclobutadiene-iron and -ruthenium Derivatives + (n = 1-3, L = phosphorus donor)

DOI: 10.1039/DT9810000034

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Journal of the Chemical Society, Dalton Transactions p. 34 - 39 (1981)

Update date:2022-08-02

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Authors:

Connelly, Neil G.

Kelly, Raymond L.

Whitely, Mark W.

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Article abstract of DOI:10.1039/DT9810000034

The tetraphenylcyclobutadiene complexes 4-C4Ph4)> <1: M=Fe, n=1, L=PPh3 or P(OMe)3; M=Fe, n=2, L=P(OMe)3; M=Ru, n=2 or 3, L= P(OMe)3> undergo reversible one-electron oxidation, at the platinum electrode in CH2Cl2, to give the param

Full text of DOI:10.1039/DT9810000034

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