Amine Addition to Unsymmetrical Benzoquinones

DOI: 10.1021/jo00326a029

Source and publish data:

Journal of Organic Chemistry p. 2745 - 2752 (1981)

Update date:2022-08-04

Topics:

Authors:

Luly, Jay R.

Rapoport, Henry

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Article abstract of DOI:10.1021/jo00326a029

New routes to 2-methoxy-3-methyl-1,4-benzoquinone and 4-methoxy-3-methyl-1,2-benzoquinone have been developed.Both quinones undergo highly regioselective oxidative amination with pyrrolidine and copper acetate, yielding aminoquinones related to the mitomy

Full text of DOI:10.1021/jo00326a029

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