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Acknowledgments
This work was financially supported by the Fonds der Chemischen
Industrie (Liebig fellowship to G. M.), the Evonik Foundation
(Ph.D. fellowship to J. H.), and the Polytechnische Gesellschaft
Frankfurt am Main (Ph.D. fellowship to T. B.). We would like to
thank Rockwood Lithium (Frankfurt), BASF (Ludwigshafen) and
Evonik Industries (Darmstadt) for the generous gift of chemicals.
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[19] Analytically pure samples of the hemiaminal can be obtained
by recrystallization (n-hexane/dichloromethane, 9:1).
[20] The reduced yield is associated with partial decomposition of
hemiaminal 7a during the prolonged aqueous workup for the
reaction performed on a Ͼ10 mmol scale.
Received: May 20, 2015
Published Online: June 24, 2015
Eur. J. Org. Chem. 2015, 4624–4627
© 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
www.eurjoc.org
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