Thiones as superdipolarophiles. Rates and equilibria of nitrone cycloadditions to thioketones

DOI: 10.1021/ja00143a008

Source and publish data:

Journal of the American Chemical Society p. 9671 - 9678 (1995)

Update date:2022-08-03

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Authors:

Huisgen, Rolf

Fisera, Lubor

Giera, Henry

Sustmann, Reiner

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Article abstract of DOI:10.1021/ja00143a008

1,3-Dipolar cycloadditions of N-methyl-C,C-diphenylnitrone (15) and N-methyl-C-phenylnitrone (16) with aliphatic thioketones are equilibrium reactions. The 1,4,2-oxathiazolidines were characterized and their dissociation constants measured by ¹

Full text of DOI:10.1021/ja00143a008

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