NMR study of kinetic HH/HD/DH/DD isotope effects on the tautomerism of acetylporphyrin: Evidence for a stepwise double proton transfer

DOI: 10.1021/ja00064a018

Source and publish data:

Journal of the American Chemical Society p. 4554 - 4565 (1993)

Update date:2022-08-04

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Authors:

Schlabach, Martin

Limbach, Hans-Heinrich

Bunnenberg, Edward

Shu, Arthur Y.L.

Tolf, Bo-Ragnar

Djerassi, Carl

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Article abstract of DOI:10.1021/ja00064a018

The kinetic HH/HD/DH/DD isotope effects of an intramolecular reversible nondegenerate double proton transfer reaction are described. The molecule studied is 8-acetyl-3,13,17-tris[2-(methoxycarbonyl)ethyl]-2,7,12,18-tetramethyl-(21H,23H)- Porphyrin (acetyl

Full text of DOI:10.1021/ja00064a018

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