Journal of Molecular Structure p. 69 - 73 (2002)
Update date:2022-08-03
Topics:
Grofcsik, András
Baranyai, Péter
Bitter, István
Grün, Alajos
K?szegi, éva
Kubinyi, Miklós
Pál, Krisztina
Vidóczy, Tamás
A new spiropyran derivative containing a calixcrown ring has been synthesised. Thermal conversion from merocyanine to the spiropyran form was studied in ethanol and in acetonitrile, and equilibrium and kinetic data were compared with those of the parent 6-nitrospiropyran. The kinetics of thermal decay of the merocyanine form of the calixcrown-spiropyran molecule shows a biexponential character in both solvents, while the decay is much slower in ethanol than in acetonitrile.
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