Chemistry Letters p. 193 - 196 (1981)
Update date:2022-08-05
Topics:
Komiya, Sanshiro
Yamamoto, Akio
Yamamoto, Takakazu
Acyl(carboxylato)nickel(II) and -palladium(II) complexes, M(COR) (OCOR')L2 2 are prepared by 1:1 reactions of MR(OCOR')L2 1 with CO at -78 deg C, whereas similar reactions in the presence of excess CO at room temperature afford the reductive elimination products, RCOOCOR'.Acid anhydrides add oxidatively to an Ni())-complex to afford a complex of the type 2.
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