
Tetrahedron Letters p. 405 - 408 (1981)
Update date:2022-09-26
Topics:
Kedzierski, B.
Thakker, D. R.
Armstrong, R. N.
Jerina, D. M.
Application of the exciton chirality rule has allowed assignment of absolute configuration to (+)-trans-(4R,5R)-dihydroxy-4,5-dihydrobenzopyrene, a mammalian metabolite of the hydrocarbon.The cis 4,5-dihydrodiol and 4,5-oxide are also assigned based on correlation with the trans dihydrodiol.
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