Tetrahedron Letters p. 9565 - 9566 (1995)
Update date:2022-08-03
Topics:
Sarobe, Martin
Snoeijer, Judith D.
Jenneskens, Leonardus W.
Zwikker, Jan W.
Wesseling, Jolanda
Flash Vacuum Thermolysis of 1,5-bis-(1-chloroethenyl)anthracene (6) gives cyclopent[hi]aceanthrylene (2) which at T ≥ 900°C rearranges to cyclopent[hi]acephenanthrylene (1). This conversion occurs more readily than that of the monocyclopenta-fused aceanthrylene to acephenanthrylene.
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(1968)Doi:10.1021/acs.orglett.8b03046
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(1968)Doi:10.1021/jm970041e
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