Journal of the Chemical Society. Perkin transactions I p. 785 - 788 (1981)
Update date:2022-08-05
Topics:
Michie, Jacqui K.
Miller, Allen J.
The reaction of equimolar amounts of benzaldehyde, phosphorus trichloride, and acetic anhydride has been shown to involve successive formation of benzylidene diacetate (4) and α-chlorobehzyl acetate (5).By an Arbusov reaction, the latter is converted into the dimer (3), previously recognised as the precursor of α-hydroxybenzylphosphonic acid (1a), the known product of an aqueous work-up.A simple preparation of α-chlorobenzyl acetate (5) is described.
View MoreXi'an Galaxy Chemicals CO., Ltd
Contact:86-29-89380370
Address:No.8, Gaoxin three road, Xi'an city.
JiangXi Hong Run Chemical Co., Ltd
Contact:+86-0791-88521351
Address:XingHuo industrial zone in YongXiu county
ShanDong XinDa Chemical CO.,LTD(expird)
Contact:086-0311-87580543
Address:No.168, High Technology Development Zone Jinan Shandong China
LIANYUNGANG YC FINE CHEMICAL CO., LTD
Contact:+86-518-858 99188
Address:Shangdong Modern Bldg, South Greenpark Road, Lianyungang, Jiangsu Pro. China
Shanghai Dianyang Industry Co.,ltd
Contact:+86 21 6492 4669
Address:Chejing RD, Songjiang District, Shanghai, China
Doi:10.1002/hlca.19320150181
(1932)Doi:10.1246/bcsj.54.170
(1981)Doi:10.1021/jo00322a023
(1981)Doi:10.1021/ja01576a027
(1957)Doi:10.1002/anie.201611186
(2017)Doi:10.1021/jo00323a017
(1981)