Journal of the Chemical Society. Perkin transactions I p. 785 - 788 (1981)
Update date:2022-08-05
Topics:
Michie, Jacqui K.
Miller, Allen J.
The reaction of equimolar amounts of benzaldehyde, phosphorus trichloride, and acetic anhydride has been shown to involve successive formation of benzylidene diacetate (4) and α-chlorobehzyl acetate (5).By an Arbusov reaction, the latter is converted into the dimer (3), previously recognised as the precursor of α-hydroxybenzylphosphonic acid (1a), the known product of an aqueous work-up.A simple preparation of α-chlorobenzyl acetate (5) is described.
View MoreHeliosense Biotechnologies, Inc.
website:https://www.heliosense.com/
Contact:+86-592-5667290
Address:Xiamen Torch Hi-tech Zone Venture Weiye Building S506
JiangXi Keyuan Biopharma Co., LTD.
Contact:+86-563-6833666
Address:Guangde Fine Chemical Zone, Anhui Province, China
Chongqing Changfeng Chemical Co., Ltd.
website:http://www.changfengchem.com
Contact:+86-23-67896333
Address:30th Floor, Longhu Ziduxingzuo Building A, 1st Branch,YuSong Rd., Yubei District, Chongqing, China
Contact:+86-025-85553873
Address:Building 27, NO.699-18 XuanWu Avenue, Nanjing, Jiangsu, P.R.China.
Contact:+86-021-50792271
Address:Building 24A, 300 Chuantu Road, Chuansha, Pudong new area, Shanghai, China, 201202
Doi:10.1002/hlca.19320150181
(1932)Doi:10.1246/bcsj.54.170
(1981)Doi:10.1021/jo00322a023
(1981)Doi:10.1021/ja01576a027
(1957)Doi:10.1002/anie.201611186
(2017)Doi:10.1021/jo00323a017
(1981)
