Journal of the Chemical Society. Perkin transactions I p. 785 - 788 (1981)
Update date:2022-08-05
Topics:
Michie, Jacqui K.
Miller, Allen J.
The reaction of equimolar amounts of benzaldehyde, phosphorus trichloride, and acetic anhydride has been shown to involve successive formation of benzylidene diacetate (4) and α-chlorobehzyl acetate (5).By an Arbusov reaction, the latter is converted into the dimer (3), previously recognised as the precursor of α-hydroxybenzylphosphonic acid (1a), the known product of an aqueous work-up.A simple preparation of α-chlorobenzyl acetate (5) is described.
View MoreZhejiang Golden-Shell Pharmaceutical Co.,Ltd.
Contact:+86-576-87501888 / 87501988
Address:No.89 Zhongxing Road. Li'ao, Yuhuan, Zhejiang, China
Contact:
Address:308# dongwu avenue dongxihu district wuhan city
Jinan Baozhao Pharmaceutical Co., Ltd
Contact:0086-531-86397156 82371858 82371868
Address:Huaneng Road, Jinan, Shandong ,China
Xiamen XM-Innovation Chemical Co., Ltd
Contact:+86-592-3216205
Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C
Wuxi Pharma-Trading Import & Export Co.,Ltd.
Contact:+86-510-82304590 82716390
Address:Room 523,Youzu Alliance Building,No.88 Renmin Zhonglu,Wuxi,Jiangsu,China
Doi:10.1002/hlca.19320150181
(1932)Doi:10.1246/bcsj.54.170
(1981)Doi:10.1021/jo00322a023
(1981)Doi:10.1021/ja01576a027
(1957)Doi:10.1002/anie.201611186
(2017)Doi:10.1021/jo00323a017
(1981)
