Tetrahedron Letters p. 779 - 782 (1981)
Update date:2022-08-03
Topics:
Birch, Arthur J.
Stephenson, G. Richard
Optically active tricarbonyl(cyclohexadienyl)iron(1+) salts I, II and III are examples of olefin complexes with molecular asymmetry due to coordination with a transition metal.Their reactions serve to direct the eventual specific formation of a new chiral centre of known absolute configuration.The absolute configuration of the 2-methoxy-5-methyl salt I is defined and its application to the asymmetric synthesis of γ-disubstituted cyclohexanones is described.
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Doi:10.1016/j.carbpol.2011.09.071
(2012)Doi:10.1016/S0008-6215(00)86026-7
(1981)Doi:10.1007/BF00949602
(1981)Doi:10.1021/jo00335a037
(1981)Doi:10.1016/S0040-4039(01)90461-7
(1981)Doi:10.1016/S0022-1139(00)81290-7
(1981)
