Journal of Organometallic Chemistry p. 297 - 308 (1981)
Update date:2022-08-02
Topics:
Klei, E.
Telgen, J. H.
Teuben, J. H.
Reaction of Cp2TiCl with RLi (R = -CH3, -C2H5, -n-C4H9, -s-C4H9, -t-C4H9) yields the thermally instable TiIII compounds Cp2TiR.Reaction of these compounds with 2,6-xylylisocyanide, phenylisocyanate or carbon dioxide results in insertion of these ligands into the Ti-alkyl bond with formation of iminoacyl, amido and carboxylato derivatives, respectively.In the reaction with ketones a pinocol-type dimerisation is observed.
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Doi:10.1080/10426509808035736
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(1960)Doi:10.1246/bcsj.54.1711
(1981)Doi:10.1081/CAR-200030087
(2004)Doi:10.1016/j.bmcl.2009.05.092
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(1981)
