Journal of Organometallic Chemistry p. 297 - 308 (1981)
Update date:2022-08-02
Topics:
Klei, E.
Telgen, J. H.
Teuben, J. H.
Reaction of Cp2TiCl with RLi (R = -CH3, -C2H5, -n-C4H9, -s-C4H9, -t-C4H9) yields the thermally instable TiIII compounds Cp2TiR.Reaction of these compounds with 2,6-xylylisocyanide, phenylisocyanate or carbon dioxide results in insertion of these ligands into the Ti-alkyl bond with formation of iminoacyl, amido and carboxylato derivatives, respectively.In the reaction with ketones a pinocol-type dimerisation is observed.
Shenzhen HwaGen Pharmaceutical Co., Ltd
website:http://www.rafflespt.com
Contact:+86-752-5538396
Address:Guangdong Huizhou China
Contact:86-28-61993785
Address:No.70-13-21, North Section, Erhuan
Dongying J&M Chemical Co., Ltd,
Contact:546-8551108
Address:Room 1219, Zisheng Mansion, Zibo Road, Dongying, Shandong, China
Jinan Jinguilin Chemical Co.,Ltd
Contact:+86-531-81188412
Address:3rd floor of Torch Building, Huanyuan Rd, City of Jinan
Ningbo Inno Pharmchem Co., Ltd.
Contact:86-574-87319282
Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
Doi:10.1080/10426509808035736
(1998)Doi:10.1139/v60-278
(1960)Doi:10.1246/bcsj.54.1711
(1981)Doi:10.1081/CAR-200030087
(2004)Doi:10.1016/j.bmcl.2009.05.092
(2009)Doi:10.1021/jo00337a026
(1981)
