Journal of Organometallic Chemistry p. 297 - 308 (1981)
Update date:2022-08-02
Topics:
Klei, E.
Telgen, J. H.
Teuben, J. H.
Reaction of Cp2TiCl with RLi (R = -CH3, -C2H5, -n-C4H9, -s-C4H9, -t-C4H9) yields the thermally instable TiIII compounds Cp2TiR.Reaction of these compounds with 2,6-xylylisocyanide, phenylisocyanate or carbon dioxide results in insertion of these ligands into the Ti-alkyl bond with formation of iminoacyl, amido and carboxylato derivatives, respectively.In the reaction with ketones a pinocol-type dimerisation is observed.
Springchem New Material Technology Co.,Limited
website:http://www.spring-chem.com
Contact:86-21-62885108
Address:602B, Building 1, No. 641, Tianshan Road
Suzhou SuKaiLu Chemical Technology Co., Ltd.
Contact:+86-512-62766020
Address:Floor 4, Building 1, Xinyi Pharmaceutical Valley Wisdom Industrial Park, 415 Changyang Street, Suzhou Industrial Park, Jiangsu Province
Changzhou Welton Chemical Co., Ltd,
Contact:0086-519-85910828,85920537,85912897
Address:No.8 Jinlong Road, Binjiang Park, Changzhou, Jiangsu, China.
Contact:0086-357-6662688
Address:Zhaocheng town, Hongtong County, Linfen City, Shanxi Province
Tianjin Ingenochem Technology Co.,Ltd
Contact:+86-22-23677060
Address:Hitech Green Industry Park K2-9-602, Nankai district
Doi:10.1080/10426509808035736
(1998)Doi:10.1139/v60-278
(1960)Doi:10.1246/bcsj.54.1711
(1981)Doi:10.1081/CAR-200030087
(2004)Doi:10.1016/j.bmcl.2009.05.092
(2009)Doi:10.1021/jo00337a026
(1981)
