Unexpectedly high diastereomeric induction in the Diels-Alder reaction of quinones with chiral aryl containing 1-alkoxy-3-trimethylsilyloxybuta-1,3-dienes

DOI: 10.1016/S0040-4039(00)97288-5

Source and publish data:

Tetrahedron Letters p. 7233 - 7236 (1990)

Update date:2022-08-04

Topics:

Authors:

De Bie De Bie

Van Strijdonck

Seerden Seerden

Beurskens

Scheeren

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Article abstract of DOI:10.1016/S0040-4039(00)97288-5

Chiral 1-alkoxy-3-trimethylsilyloxybuta-1,3-dienes induce a high diastereomeric excess in the cycioaddition with quinones when the chiral alkoxy group is of the type OCH(CH₃)R with R = aryl. Also forR =vinyl. CH₂OCH₃ the f

Full text of DOI:10.1016/S0040-4039(00)97288-5

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