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Regiospecific Attack of Methoxide Ion on 4-Alkoxy-o-quinone Imines. A Novel Route to p-Quinone Monoacetals

DOI: 10.1039/c39810000425

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 425 - 426 (1981)

Update date:2022-08-03

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Authors:

Fujita, ShinsakuFujita, Shinsaku

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Article abstract of DOI:10.1039/c39810000425

In the solvolysis of 4-alkoxy-5-methyl-o-benzoquinone N-arylsulphonylimines (1a) and (1b) (NaOH-MeOH-H2O), the regiospecific attack of MeO- occurs initially on the carbon atom substituted by the alkoxy-group to produce the p-benzoquinone monoacetals (3a)

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Product name:N-(3-Hexadecyloxy-3-methoxy-4-methyl-6-oxo-cyclohexa-1,4-dienyl)-2-(2-methoxy-ethoxy)-5-nitro-benzenesulfonamide

Cas No:78826-19-4

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