-Cycloaddition of a Stabilised Vinyl Cation with Cyclopentadiene; X-Ray Crystal Structure of the 2:1 Addition Product

DOI: 10.1039/c39810000683

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 683 - 684 (1981)

Update date:2022-08-02

Topics:

Authors:

Mayr, Herbert

Wilhelm, Eberhard

Kaliba, Claus

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39810000683

Lewis acid-catalysed reaction of 1,1-dimethyl-3-phenylprop-2-ynyl chloride with cyclopentadiene yields a 2:1 addition product via <2+2>-cycloaddition of an intermediate allenyl cation.

Full text of DOI:10.1039/c39810000683

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:5-<(E)-α-Chlorbenzyliden>-6,6-dimethylbicyclo<2.2.1>hept-2-en

Cas No:78872-22-7

R&D Labs maybe for 78872-22-7

Chengdu Green technology Co.,Ltd.

Contact:86-28-82608355

Address:C9 ,Economic Headquarters, Economic Development Zone, Chengdu.
TIC Gums, Inc.

Contact:410-273-7300; 800-221-3953

Address:4609 Richlynn Dr., PO Box 369, Belcamp, MD, 21017-0369, USA
Jiangsu Allyrise Pharmaceutical Co., Ltd.(expird)

Contact:+86-523-86818997

Address:Taizhou,Jiangsu Province,CHINA
NOVASYNCS CO., LTD

Contact:0512-63006287

Address:no.88.YISHENG Road,etdz-WUJIANG,SUZHOU,CHINA
MINS GROUP CO.,LIMITED

Contact:18669908765

Address:Zibo City, Shandong Province, P.R.China

Relevant to this article

Bioreduction of α-Acetoxymethyl Enones: Proposal for an S_N2′ Mechanism Catalyzed by Enereductase

Doi:10.1002/adsc.201600601
(2016)
Caged trans-4-hydroxy-2-nonenal

Doi:10.1021/ol048478l
(2004)
Synthesis and AMPA receptor antagonistic activity of a novel 7-imidazolyl-6-trifluoromethyl quinoxalinecarboxylic acid with a substituted phenyl group and improved its good physicochemical properties by introduced CF₃ group

Doi:10.1016/j.bmcl.2004.07.093
(2004)
Synthesis and spectroscopic studies of 5-arylidene-3-substituted tetramic acids as possible substrates for catalytic asymmetric hydrogenation

Doi:10.1002/jhet.5570380527
(2001)
Stereocontrolled Synthesis of 5α- and 5β-Substituted Kainic Acids

Doi:10.1021/jo982109j
(1999)
Dinuclear Elimination from Rhenium Hydrides and AlMe3: Rhenium/Aluminum Polyhydrides

Doi:10.1021/ja00338a021
(1984)

Article Doi