-Cycloaddition of a Stabilised Vinyl Cation with Cyclopentadiene; X-Ray Crystal Structure of the 2:1 Addition Product

DOI: 10.1039/c39810000683

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 683 - 684 (1981)

Update date:2022-08-02

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Authors:

Mayr, Herbert

Wilhelm, Eberhard

Kaliba, Claus

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Article abstract of DOI:10.1039/c39810000683

Lewis acid-catalysed reaction of 1,1-dimethyl-3-phenylprop-2-ynyl chloride with cyclopentadiene yields a 2:1 addition product via <2+2>-cycloaddition of an intermediate allenyl cation.

Full text of DOI:10.1039/c39810000683

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