Leaving group based intramolecular glycoside bond formation

DOI: 10.1016/S0040-4039(00)61687-8

Source and publish data:

Tetrahedron Letters p. 6733 - 6736 (1993)

Update date:2022-08-03

Topics:

Authors:

Behrendt, Michael E.

Schmidt, Richard R.

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Article abstract of DOI:10.1016/S0040-4039(00)61687-8

Sterically crowded β-hydroxy-substituted glucosyl carboxylates 4α,β furnish with strong alkylating agents 5a-c in the presence of base diastereoselectively α- or β-glucosides 6a-c, respectively; in addition, β-lactone 7 is formed. The reaction is discusse

Full text of DOI:10.1016/S0040-4039(00)61687-8

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