Tetrahedron Letters p. 1885 - 1888 (1981)
Update date:2022-08-05
Topics:
Pardo, Simon N.
Ghosh, Subrata
Salomon, Robert G.
Diethyl allylmalonates or 2 arylalkanoic esters are prepared in good yield by reductive α-deoxygenation of the corresponding α-acetoxy or α-alkoxy esters.Since the intermediate ester enolates are generated under aprotic conditions, a one pot reductive-alkylation is also possible.One application of this procedure allows diethyl oxomalonate to serve as a conjunctive reagent for stitching together an alkene and an alkyl halide with a malonyl group as linchpin.
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